Spectrophotometric determination of chromium as the chromium-peroxo-4-(2-pyridylazo)resorcinol complex
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Catalytic Spectrophotometric Determination of Chromium
chromium(III) up to 100 ng mL−1, and for chromium(VI) up to 200 ng mL−1) were obtained, using the “fixed time” method with detection limits of 4.9 ng mL−1 and 3.8 ng mL−1, respectively. The results suggest that at the reaction conditions chromium(VI) is reduced and chromium(III) is oxidized to an intermediate oxidation state and the catalytic action of chromium is due to the formation of an act...
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A very specific, selective, simple, and inexpensive procedure was developed for the speciation of CrVI and CrIII. This method is based on the quantitative extraction of chromate and CrIII (previously oxidized to CrVI) as a tetrabutylammonium-chromate ion-pair in methyl isobutyl ketone (MIBK), and then back extraction and preconcentration with an acidic diphenylcarbazide (DPC) solution. Back ext...
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Um método espectrofotométrico simples, rápido e sensível foi desenvolvido para a determinação traço de cromo usando azul de Variamina como reagente cromogenico. O método proposto consiste na reação de cromo(VI) com iodeto de potássio, em meio ácido, liberando iodeto que então oxida o azul de Variamina formando um composto de cor violeta com o máximo de absorção em 556 nm. A lei de Beer é obedec...
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ژورنال
عنوان ژورنال: Fresenius' Zeitschrift f�r Analytische Chemie
سال: 1980
ISSN: 0016-1152,1618-2650
DOI: 10.1007/bf00480608